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贵州贞丰县水银洞金矿床成矿特征和金的超常富集机制研究
其他题名Characteristics and Model for Shuiyindong Gold Deposit in southwestern Guizhou, China
夏勇
学位类型博士
2005
学位授予单位中国科学院地球化学研究所
学位授予地点中国科学院地球化学研究所
学位名称博士
学位专业矿床地球化学
摘要黔西南地区是我国最重要的卡林型金矿床集中区,在该区卡林型金矿床具有断裂型和层控型两大类。断裂型金矿床产于高角度压扭性断裂中,赋矿层位一般为中、下三叠统地层,容矿岩石主要是泥质粉砂岩和粉砂质泥岩。层控型金矿床主要产于上二叠统地层中,容矿岩石主要是不纯的生物碎屑灰岩,背斜控矿明显。由于目前断裂型金矿一研究程度高,而层控型金矿研究程度低.近年来在层控型金矿床中一些大型和特大型矿床以及富矿体和高拮位矿石的新发现,使层控型金矿床成为黔西南卡林型金矿床的重要和具有特征的类型。因此,作者选择了水银洞金矿床这个大型较富的一卜林型金矿床进行系统研究,对其成矿特征和金的超常富集机制获得以下认识:1.金矿床受构造与有利岩性组合的双重控制。金矿床位于灰家堡背斜核部,矿体产在粘土岩叶灰岩一粘土岩组合之灰岩中,以层状·似层状为主。一些低角度的断层控制了少量的断裂型金矿体。2.金矿床具有低温成矿特征,主成矿期流体包裹体的均一温度2约℃士,出现硅化、白云右化、黄铁矿化和粘土化等围岩蚀变,特征的Au-As-11g-Tl元素组合。矿石中Au主要不均匀分布在富砷环带中。纳米金可能是水银洞金矿床金的主要存在形式,并且快速沉淀在几个微米宽的细小黄铁矿中的砷黄铁矿环带和几一卜微米小的热液毒砂中。成矿条件的骤变和黄铁矿的吸附是重要因素。3.成矿流体具有低温低盐度和较高压力和富挥发份的特点,均一温度在220 ℃士,盐度在6士W七%NoCI、,压力为1.6士0.4Kbal"s,在Vc,I4+限川j』包裹体中Cll。含量高达63mole%、N:为18nlole%、C0;为19mole%。高压和富挥发份促使成矿流体从深部迁移至控矿背斜核部,并由于断层的作用挥发份的快速逃逸,压力骤降,促使流体快速卸载,一形成金的快速沉淀,形成微细浸染壮的原生金矿石:4.成矿物质主要来自深部。系卿勺岩矿地球化学研究和同位素示踪显示断,成矿一物质可能是燕山期构造岩浆活动形成的成矿流体(慢源铅)上升溶解地壳铅和混入地壳淋滤错大而形成的壳物质的混合;容矿地层均为正常沉积作用形成,. 没有发现具有特殊意义的沉积层(矿源层);成矿特征元素Au、As、51。、Tl和伴生的其他热液活动元素来自热液的带入,没有证据显示出地层岩石中有大规模的成矿元素迁出。5.区域_日也壳的活动性,长时期的热状态,有利于大范围内形成超压成矿流体。而地壳的伸展拉张促使了基底早己有的断裂再度复活,并与成矿期断裂一起切穿地壳,为深部超压成矿流体涌入成矿体系提供了必要的通道和热动力条件,使断裂系统就象抽水泵一样,汇聚成矿流体进入地壳上部成矿体系。由于本地区浅层构造的复杂性,导致成矿现象复杂多样,常形成而状矿化,大区域上呈“金三角”。不象羊国西部地区卡林型金矿产出区,金矿在区域上呈线形分布,众多超大型金矿被发现。
其他摘要The southwestern Guizhou Province is the most important metallogenic province of Carlin-type gold deposits in China. There are two kinds of Carlin-type gold deposits: fault-controlled and stratabound. The fault-controlled Carlin-type gold deposits are localized at the compressive shear faults and hosted in siltstones and silty mudstones of Middle or Lower Triassic. The stratabound Carlin-type gold deposits are controlled by anticlines and hosted in silty bioclastic limstones of Upper Permian. There are lots of studies on fault-controlled gold deposits, but a few on stratabound deposits. Recently, the new findings of some large scale stratabound gold deposits with high grade orebodies and ores make stratabound gold deposits as an important and characteristic kind of Carlin-type gold deposits in the area. The Shuiyindong gold deposit, the most important stratabound Carlin-type gold deposit, has been studied systematically, and the major understandings on its characteristics and model for it are as follows: 1. The gold deposit is controlled by both the structure and favorable lithology. It was located nearby the core of the Huijiabao anticline and orebodies are hosted in the limestone within the sedimentary series of clayrock-*-limestone-" clay rock. Most of orebodies are stratiform ones. However, some orebodies with less importance are controlled by low angle faults and called as fault-controlled orebodies. 2. The gold mineralization occurred under low-temperature with Th of 220°C±. Common hydrothermal alteration types such as silicification, dolomitization, and pyritization have been observed. The gold deposit has characteristic elemental assemblages of Au-As-Hg-Tl. Gold mainly presents as native gold, as tiny inclusions in As-rich pyrite rims on earlier stage pyrites and arsenopyrites. The As-rich pyrites and arsenopyrites are also very small (about several tens of fi m), which indicates that gold deposition might be due to quick change of metallogenetic conditions. 3. Fluid inclusions in vein quartz from the gold deposit are rich CO2, CH4, N2, (VCTI4+N2ICO2 inclusions have CH4 of 63 mo!e%, N?. of 18 mole%, CO2 of 19 mole%, respectively.), Th of 220°Ci , salinities of 6 wt.% ±, and minimum pressures of 1.6 ± 0.4 khar., indicating that the fluid is a overpressured one. The overpressured fluid is favorable factor for gold mineralzation, 4. Studies of geochemistry and isotope compositions indicate that the ore-bearing materials and fluids of the gold deposit mainly originated from plutonic source, and possess a mixing features with the strata matter during transportation from mantle to crust. The host rocks are common sedimentary rocks, and no evidence has been found for (hat there are some significant strata(ore-source bed), as well as for that ore-bearing materials originated from host strata. 5. The activity and heat-state of Earth's crust in long period are favorable for the formation of overpressured fluids in a large area, and extensive structures drove the fluids into ore-forming system and made gold deposits formed. The complexity of structural movement in upper crust of southwestern Guizhou, resulted in a complicated gold mineralzations. Unlike Nevada in western USA., there is a "Gold Triangle", but still no world-class Carlin-type gold deposits has been found in southwestern Guizhou.
页数114
语种中文
文献类型学位论文
条目标识符http://ir.gyig.ac.cn/handle/352002/3732
专题研究生_研究生_学位论文
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夏勇. 贵州贞丰县水银洞金矿床成矿特征和金的超常富集机制研究[D]. 中国科学院地球化学研究所. 中国科学院地球化学研究所,2005.
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