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云南都龙锡锌多金属矿床成矿物质来源研究
何芳
导师张乾
2014
学位授予单位中国科学院研究生院
学位授予地点北京
学位名称硕士
学位专业地球化学
关键词都龙锡锌多金属矿床 成矿物质来源 成矿年代 地球化学证据 岩浆热液成因
摘要云南都龙锡锌多金属矿床位于云南省都龙镇境内,是滇东南三大多金属矿床之一(个旧、白牛厂和都龙)。该矿床以锡、锌为主,伴生银、铟、镉、铜、铅、镓、锗等20余种有益组分。矽卡岩型矿体主要呈层状、似层状赋存于新寨岩组的片岩夹大理岩中。自上世纪80年代后期以来,前人对该矿床进行了大量研究,但在矿床成因认识方面仍然存在较大分歧,岩浆热液成因(宋焕斌等,1988,1989;张洪培等,2006)、喷流沉积成因(周建平等,1997,1998;贾福聚等,2010)和热水沉积-区域变质-岩浆热液多成因(刘玉平等,1998,2000,2007)三种观点相持不下。矿床成因的不确定使得地勘部门对下一步去哪儿找矿感到十分困惑。本文在云南华联锌铟股份有限公司委托的“云南马关老君山西部锡锌多金属成矿作用研究与找矿预测(KY20120910)”和矿床地球化学重点实验室“十二五”项目群(SKLODG-ZY125-04)的支持下,在野外地质考察和岩矿鉴定的基础上,对该矿床开展了系统的稀土元素分析、碳氧同位素分析、硫同位素分析、铅同位素分析和辉钼矿Re-Os年代学分析,在确定矿质来源的基础上,综合分析探讨矿床成因,建立成矿模式。主要取得以下认识: (1)矿床地球化学特征支持岩浆热液成矿 矿石矿物和老君山花岗岩体的稀土配分模式具高度一致性,均显示Eu负异常和轻稀土较富集特征,两者经历了相似的地质地球化学过程,说明成矿物质可能主要来源于与老君山花岗岩有关的酸性岩浆; 含矿方解石δ13C变化于-3.09‰~-8.57‰之间,均值-6.57‰,与岩浆碳同位素组成一致,明显偏离大理岩分布范围; 硫化物单矿物δ34S变化小,靠近零值,具岩浆硫特性; 矿石矿物铅同位素组成分布集中,具有均一的较浅源区,与老君山花岗岩长石铅同位素组成一致,而与基底片麻岩长石铅同位素组成有一定偏离,表明该矿床的Pb主要来源于老君山花岗岩,基底片麻岩对Pb贡献很小;片岩和大理岩分布分散,明显偏离矿石矿物铅同位素组成,基本对该矿床的铅来源没有贡献。 (2)矿床的形成时代与老君山花岗岩一致 获得2件辉钼矿的Re-Os模式年龄为(93.557±2.645)Ma和(93.662±1.241)Ma,结合项目组取得的锡石U-Pb年龄,证明了成矿时代与老君山花岗岩年龄在误差范围内一致,表明该矿床的形成与岩浆作用关系密切。 (3)野外地质证据可以否定寒武纪喷流沉积成矿 热水喷流沉积观点最主要的证据是该矿床的矿体呈层状、似层状产出,同时存在诸如条带状、层纹状矿石构造。野外研究发现,虽然从宏观上看矿体呈层状、似层状,但是几乎所有的矿体都与矽卡岩相伴产出,有些矿体是典型的矽卡岩型矿体,矿体严格受断裂构造控制,其产状与地层并不一致。在许多地段发现矽卡岩型矿体明显切穿地层,靠近矿体的大理岩中穿插大量碳酸盐细-网脉或呈现“漂白”现象,这种细-网脉中的方解石的C-O同位素组成也显示岩浆来源。这些地质现象并不支持同生喷流沉积成矿。 (4)矿床成因 矿质来源、成矿年代和野外地质证据三个方面一致表明,都龙锡锌多金属矿床成矿物质主要来源与老君山花岗岩,矿床形成主要与岩浆作用有。因此,矿床属于典型的岩浆热液矿床。因此,下一步的找矿应该围绕(隐伏)岩体展开。 本研究与以往的研究不同的是:① 以足够具有代表性的S-C-O-Pb同位素样品数量论证并肯定了该矿床的矿质来源,其中首次对该矿床进行的C-O同位素组成取得了较好的效果;②室内地球化学证据与野外地质特征紧密结合,否定了喷流沉积成矿作用,肯定了岩浆热液成矿观点;③ 指出了围绕隐伏岩体找矿的新认识。
其他摘要The Dulong Sn-Zn pollymetallic deposit, located in Maguan county, Yunnan, is one of the biggest polymetallic depostits at Southeastern Yunnan, which is characterized by large scale Sn, Zn reserves with lots of beneficial elemengts(Ag, In, Cd, Cu, Pb, Ga, Ge, etc). Skarn ore bodies being with stratiform and stratoid occurred in Xinzhai formation’s schist interlated with marble. Since 1980s, a lot of studies were worked about the deposit, but there is a big controversy about the deposit genesis among magmatic hydrothermal origin (Song huanbin et al., 1988,1989; Zhang hongpei et al., 2006), jet sedimentary origin (Zhou jianping et al., 1997,1998; Jia fuju et al.,2010) and hot water depostition-regional metamorphism-magmatic hydrothermal origion (Liu yuping et al., 1998, 2000, 2007) which makes the survey department confused where to prospect next.Under the support of “mineralization research and prospectiong prediction of Laojunshan western Sn-Zn polymetallic, Maguan county, Yunnan” (KY20120910) commissioned by the Yunnan Hualian Zinc Indium Limited Liability Company and “shi er wu” project group of State Key Laboratory of Ore Deposit Geochemistry (SKLODG-ZY125-04), Based on field geology and ore microscope analysis, analyses on REE, C-O isotope, S isotope, Pb isotope and Re-Os dating of molybdenite have been studied systematically, based on certainty of sources of ore-forming material, we analyzed comprehensively the deposit genesis and established metallogenic model. The main conclusions are listed below: (1) Deposit geochemistry characteristics support magmatic hydrothermal origion REE characteristics of ore mineral and Laojunshan granite body have high consistency, both show the negative Eu anomalies and light REE enrichment, indicating both of them experienced a similar geological and geochemical processes and the main sources of ore-forming are from acidic magma related with Laojunshan granite; δ13C of mineralized cacite ranges from -3.09‰ to -8.57‰,averaged -6.57‰, which is consistent with magma and deviated significantly from the distribution of marble; δ34S of sulphide minerals have little change, close to zero valve with magmatic sulfur characteristic; lead isotope compositions of ore minerals have concentrated distribution with a uniform shallow source region, consistent with the lead isotope compositions of feldspar of magma, otherwise, they deviated from gneiss lead isotope compositions, indicating that Pb of the deposit mainly come from Laojunshan granite; Schist and marble with scattered distribution deviated significantly from the ore minerals, which suggested schist and marble nearly have nothing with lead source of the deposit. (2)Chronology of the deposit is consistent with the Laojunshan granite Two molybdenite Re-Os model ages are (93.557±2.645)Ma and (93.662±1.241)Ma, which is within the error range contracted to Laojunshan granite, suggesting that the deposit formation was closely related with the magmatism. (3) Field geology evidence deny Cambrian SEDEX mineralization The main evidence of SEDEX origion were that ore body is stratriform or stratoid and the presence of banded, lamellar structures. Field geology found ore bodies are layered on macroscopical, but almost the bodies are accompanied with skarn, some of which are typical skarn ore bodies, and they extremely are controlled by faults and the occurrence is not the same with the formation; In addition, skarn ore bodies were found cutting through the formation, marble near the ore body interspersed with multiple carbonate veins or showed the “bleaching” phenomenon. All above consistently show absence of SEDEX origion. (4)Genesis of the Dulong Sn-Zn polymetallic deposit REE, isotope geochemistry, chronology studies and field geology evidence indicat that the sources of ore-forming mainly came from Laojunshan granite, the deposit formation had a close relation with magma activities. Therefore, the Dulong Sn-Zn polymetallic deposit belongs to the
学科领域矿床地球化学
语种中文
文献类型学位论文
条目标识符http://ir.gyig.ac.cn/handle/352002/5901
专题研究生_研究生_学位论文
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何芳. 云南都龙锡锌多金属矿床成矿物质来源研究[D]. 北京. 中国科学院研究生院,2014.
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