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新疆卡鲁安矿区伟晶岩锆石U-Pb定年、Hf同位素组成及其与哈龙花岗岩成因关系研究
马占龙
导师张辉
2014
学位授予单位中国科学院研究生院
学位授予地点北京
学位名称硕士
学位专业矿物学、岩石学、矿床学
关键词锆石u-pb定年 锆石hf同位素 花岗岩 伟晶岩 卡鲁安矿区 新疆阿尔泰
摘要中国阿尔泰造山带位于西伯利亚板块和哈萨克斯坦-准噶尔板块之间,是中亚造山带的重要组成部分。据统计区内的伟晶岩脉多达十万余条,其中具有稀有金属矿化的伟晶岩脉就达千余条。但截至目前有关阿尔泰造山带的伟晶岩成因、形成时代、岩浆物源以及形成的大地构造背景等的研究还相当缺乏。 位于中阿尔泰构造单元中的哈龙花岗岩体,是一个规模巨大的复式岩基,围绕其分布着4个伟晶岩田,分别是位于哈龙岩体东侧的柯鲁木特-吉得克伟晶岩田、阿拉山伟晶岩田,位于哈龙岩体西侧的卡鲁安-阿祖拜伟晶岩田、琼库尔伟晶岩田。这4个伟晶岩田中分布有一万余条伟晶岩脉,其中具代表性的稀有金属伟晶岩矿床,包括卡鲁安806、807号脉大型Li矿床、库卡拉盖650号脉大型Li矿床、柯鲁木特112号脉中型Li-Nb-Ta矿、佳木开碧玺矿及琼库尔1号脉中型Nb-Ta矿。空间上,在哈龙岩体西侧,由花岗岩与库鲁木提群外接触带向西,伟晶岩矿化呈现出分带性,依次出现无矿化伟晶岩、Be矿化伟晶岩、Li矿化伟晶岩、石英脉的分带特征,卡鲁安矿区伟晶岩处于Li矿化伟晶岩带。但由于缺乏系统可靠的伟晶岩、花岗岩年代学,目前不清楚该区伟晶岩脉形成时代以及与哈龙花岗岩的成因联系。 卡鲁安矿区,是一个潜在的超大型锂辉石矿床。本文旨在揭示卡鲁安矿区伟晶岩形成时代及期次,伟晶岩形成的可能物源、构造背景以及与哈龙花岗岩之间的成因关系,并试图探讨哈龙岩体成因及其形成的构造背景。 本文利用LA-ICPMS和LA-MC-ICPMS技术,开展对卡鲁安-阿阻拜伟晶岩田中4条伟晶岩脉以及哈龙岩体中锆石U-Pb定年、Hf同位素组成研究,并对哈龙花岗岩开展岩石地球化学特征研究,主要获得以下重要认识: (1) 锆石U-Pb定年结果显示,卡鲁安锂矿区805、806、807号脉的形成时代分别为216.0±2.6Ma、223.7±1.8Ma、221±15Ma,形成于三叠纪。库卡拉盖650号脉由2期伟晶岩构成,早期钠长石伟晶岩形成时代为227.9±2.6 Ma,晚期锂辉石-钠长石-锂云母伟晶岩形成时代为211.3±2.4 Ma。哈龙岩体形成时代为396.9~408.1 Ma,属早泥盆世岩浆活动的产物; (2) 所研究的卡鲁安-阿祖拜伟晶岩田中伟晶岩形成于三叠纪,与哈龙岩体形成时代之间存在>170 Ma上差异,预示它们之间不具成因上的联系; (3) 卡鲁安矿区伟晶岩脉中锆石显示较小的正εHf(t)值(+0.65~+2.50),和较大的模式年龄TDM2为1,090~1,213 Ma,相似于可可托海3号脉、柯鲁木特112号脉中锆石的Hf同位素组成,指示伟晶岩形成于陆-陆碰撞体制下,增厚地壳伸展减薄导致的减压部分熔融; (4) 在岩石地球化学上,哈龙花岗岩岩石地球化学显示出富硅(SiO2 = 71.97%~74.94%)和铝(Al3O2 = 12.13%~15.22%),全碱含量中等(K2O+Na2O = 6.69%~9.14%),相对富钾(K2O /Na2O = 1.06~1.54),低铁(Fe2O3T= 0.51%~2.58%)、镁(MgO=0.15%~0.70%)、钙(CaO = 0.59%~1.58%)、锰(MnO=0.01%~0.07%)和磷(P2O5 = 0.07%~0.23%),富集Rb、Th、U、K、Hf、Zr和LREE等元素,明显亏损Ba、Nb、Sr、P和Ti等元素,重稀土分馏不明显及有显著的Eu负异常特征;铝过饱和指数A/NCK变化于1.04~1.17,属高钾钙碱性过铝质花岗岩。哈龙花岗岩显示较大的正εHf(t)值(+7.85~+14.95),和较小的二阶段模式年龄TDM2为438~891 Ma。结合哈龙岩体的锆石U-Pb年龄和前人研究成果,提出该岩体形成于活动大陆边缘的陆弧环境。
其他摘要The Altai orogen in China is a typical region of the Central Asian Orogenic Belt (CAOB), which is situated between the Siberia block and the Kazakhstan-Junggar block. According to previous statistics, there are nearly one hundred thousand pegmatite veins exposed in the Altay area. Among them, about one thousand pegmatite veins are rare metal mineralization pegmtite. Howere, it is quite deficient of the studies on pegmatite petrogenesis, formation age , provenance and geotectonic setting until now. The Halong granite is emplaced in early Paleozoic Halong-Qinghe hypozonal magmatic arc of mid-Altay tectonic units was encompassed by four pegmatitic fields, respectively, the Kelumute-Jideke pegmatite field and Alashan pegmatite field are located at the east side of halong granite, the Kaluan-Azubai pegmaite field and Qiongkuer pegmatite field are located at the west side of halong granite. There are more than ten thousands pegmatite veins in the four pegmatite pegmaite fields. Among them, including the Kaluan No. 806 and 807 pegmatites large-sized Li deposit, the Kukalagai No. 650 pegmatite large-sized Li deposit, the Kelumute No. 112 medium-sized Li-Nb-Ta deposit, the Jiamukai tourmaline deposit, and the Qiongkuer No. 1 medium-sized Nb-Ta deposit. In space, on the west side of Halong granite, westward by the granite and the Kulumuti group outer contact zones, the pegmatite mineralization presents zonality. In turn, it is appearing that no mineralized pegmatites, Be mineralized pegmatites, Li mineralized pegmaites and quartz veins. The pegmatites of Kaluan appear in Li mineralized zone. Because of lacking of system reliable chronology of pegmatite and granite, it is still inconclusive whether pegmaites of Kaluan mining area are genetically correlated with the Halong granite. The Kaluan minging area is a potential super-large deposit. The purpose of this paper is to reveal Kaluan mining pegmatites formation ages and stages, pegmatitic provenance, tectonic setting, petrogenetic relationship between pegmatites of Kaluan and the Halong granite, and tries to explore the gensis and geotectonic setting of the Halong granite. Zircon U-Pb dating and Hf isotopes of four pegmaites from the Kaluan-Azubai pegmatite mining area were carried out by LA-ICPMS and LA-MC-ICPMS, also the systematic studies on zincon U-Pb dating and geochemistry characters of the Halong granite were carry out in this paper, the following original understanding have been obtained: (1) The U-Pb data for the zircons from the pegmatite samples by LA-ICPMS shows, that the formation ages of pegmatites, numbered 805, 806 and 807 in the Kaluan mining area, were determined to be 216.0±2.6 Ma, 223.7±1.8 Ma and 221±15 Ma, respectively, as the products of Triassic magmatic activities. For the Kukalagai No. 650 pegmatite, that it mades up of two stages of pegmatites, that is, the early albite pegmatite (227.9±2.6 Ma) and the late spodumene-albite-lepidolite pegmatite (211.3±2.4 Ma). The intrusive age of Halong granite is in the range of 396.9~408.1 Ma, as the products of Devonian magmatic activities. (2) Researched pegmatites of Kaluan-Azubai pegmaite mining area formed in Triassic. As large gaps in their formation age (>170 Ma) between pegmatites and Halong granites, it indicates that pegmatites from the Kaluan mining area have no genetic relationship with the Halong granite. (3) Zircons from the pegmatites of Kaluan mining area have lower positive εHf(t) values (+0.64~+2.50), with larger TDM2 model ages of 1,090~1,213 Ma, similar to zincon Hf isotopes of the Keketuohai NO. 3 pegmatite and the Kelumute No. 112 pegmatite, indicating that the pegmatites were created by crust thickening and decompression melting in a post-collision tectonic setting. (4) The geochemistry of Halong granites shows the characteristics of high silicon(SiO2 = 71.97%~74.94%) and aluminum(Al3O2 = 12.13%~15.22%), moderate alkali contents(K2O+Na2O = 6.69%~9.14%), relatively abundant in K(K2O /Na2O = 1.06~1.
学科领域地球深部物质与流体作用地球化学
语种中文
文献类型学位论文
条目标识符http://ir.gyig.ac.cn/handle/352002/5909
专题研究生_研究生_学位论文
推荐引用方式
GB/T 7714
马占龙. 新疆卡鲁安矿区伟晶岩锆石U-Pb定年、Hf同位素组成及其与哈龙花岗岩成因关系研究[D]. 北京. 中国科学院研究生院,2014.
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