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Raman scattering of 2H-MoS2 at simultaneous high temperature and high pressure (up to 600 K and 18.5 GPa)
JianJun Jiang; HePing Li; LiDong Dai; HaiYing Hu; ChaoShuai Zhao
2016
发表期刊AIP Advances
卷号6期号:3
摘要
The Raman spectroscopy of natural molybdenite powder was investigated at simultaneous conditions of high temperature and high pressure in a heatable diamond anvil cell(DAC), to obtain the temperature and pressure dependence of the main Raman vibrational modes (E1g,E12g,A1g, and 2LA(M)). Over our experimental temperature and pressure range (300–600 K and 1 atm−18.5 GPa), the Raman modes follow a systematic blue shift with increasing pressure, and red shift with increasing temperature. The results were calculated by three-variable linear fitting. The mutual correlation index of temperature and pressure indicates that the pressure may reduce the temperature dependence of Raman modes. New Raman bands due to structural changes emerged at about 3–4 GPa lower than seen in previous studies; this may be caused by differences in the pressure hydrostaticity and shear stress in the sample cell that promote the interlayer sliding.
学科领域地球深部物质与流体作用地球化学
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.gyig.ac.cn/handle/352002/6165
专题地球内部物质高温高压实验室_地球内部物质高温高压实验室_期刊论文
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JianJun Jiang,HePing Li,LiDong Dai,et al. Raman scattering of 2H-MoS2 at simultaneous high temperature and high pressure (up to 600 K and 18.5 GPa)[J]. AIP Advances,2016,6(3).
APA JianJun Jiang,HePing Li,LiDong Dai,HaiYing Hu,&ChaoShuai Zhao.(2016).Raman scattering of 2H-MoS2 at simultaneous high temperature and high pressure (up to 600 K and 18.5 GPa).AIP Advances,6(3).
MLA JianJun Jiang,et al."Raman scattering of 2H-MoS2 at simultaneous high temperature and high pressure (up to 600 K and 18.5 GPa)".AIP Advances 6.3(2016).
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