High Precision Determination of Mercury Isotope Ratios Using Online Mercury Vapor Generation System Coupled with Multi-collector Inductively Coupled Plasma-Mass Spectrometry

	High Precision Determination of Mercury Isotope Ratios Using Online Mercury Vapor Generation System Coupled with Multi-collector Inductively Coupled Plasma-Mass Spectrometry
	Run-Sheng YIN; Xin-Bin FENG; Delphine Foucher; Wen-Fang SHI; Zhi-Qi ZHAO; Jing WANG
	2010
发表期刊	Chinese Journal of Analytical Chemistry
卷号	38 期号:7 页码:929-934
摘要	In this study, a method for high-precision measurement of Hg isotope ratios by multiple collector inductively coupled plasma-mass spectrometry (MC-ICP-MS) with on-line Hg reduction technique was developed. The procedure was evaluated to obtain high-precision measurements that were good enough to significantly detect the anticipated small differences in Hg isotope compositions in natural samples. Typically, internal precision was better than 0.02%_° (1 RSE) on all Hg ratios investigated. The external reproducibility for standard NIST SRM3133 and UM-Almadén secondary solution, nature samples were 0.06%_° (2SD) and 0.10%_° (2SD) over a period of 7 months, respectively. The extent of fractionation has been investigated in a series of natural samples from different locations in China. The ratio ²⁰²Hg/¹⁹⁸Hg expressed as δ values (per mil deviations relative to NIST SRM 3133 Hg standard solution) displayed differences from –3.48%_° to 0.633%_°. These results indicated a wide perspective application of tracing Hg in the environment.
学科领域	环境地球化学
收录类别	SCI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.gyig.ac.cn/handle/352002/6805
专题	环境地球化学国家重点实验室_环境地球化学国家重点实验室_期刊论文环境地球化学国家重点实验室
推荐引用方式 GB/T 7714	Run-Sheng YIN,Xin-Bin FENG,Delphine Foucher,et al. High Precision Determination of Mercury Isotope Ratios Using Online Mercury Vapor Generation System Coupled with Multi-collector Inductively Coupled Plasma-Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry,2010,38(7):929-934.
APA	Run-Sheng YIN,Xin-Bin FENG,Delphine Foucher,Wen-Fang SHI,Zhi-Qi ZHAO,&Jing WANG.(2010).High Precision Determination of Mercury Isotope Ratios Using Online Mercury Vapor Generation System Coupled with Multi-collector Inductively Coupled Plasma-Mass Spectrometry.Chinese Journal of Analytical Chemistry,38(7),929-934.
MLA	Run-Sheng YIN,et al."High Precision Determination of Mercury Isotope Ratios Using Online Mercury Vapor Generation System Coupled with Multi-collector Inductively Coupled Plasma-Mass Spectrometry".Chinese Journal of Analytical Chemistry 38.7(2010):929-934.

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