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Electrochemical behaviour of chalcopyrite (CuFeS2) in FeCl3 solution at room temperature under differential stress
Qingyou Liu; Heping Li
2011
发表期刊International Journal of Mineral Processing
卷号98期号:1-2页码:82-88
摘要The electrochemical behaviour of chalcopyrite (CuFeS2) was studied by polarisation curve and electrochemical impedance spectroscopy (EIS) in FeCl3 solution at room temperature under differential stress. Experimental results showed the relation between chalcopyrite potential difference and elastic stress is ΔφCuFeS2 H = − VdP ZF . The corrosion current density and charge transfer electrical resistance increased distinctly, whereas double-layer capacitance decreased and the corrosion potential became more negative with increasing differential stress. The EIS data have been analyzed and discussed in the simple equivalent circuit model, the Randles equivalent electrical circuit model and the point defect model, respectively. The experimental results are significant for mineral processing and hydrometallurgy.
关键词Chalcopyrite Polarisation Curves Electrical Impedance Spectroscopy Differential Stress
学科领域地球深部物质与流体作用地球化学
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.gyig.ac.cn/handle/352002/7021
专题地球内部物质高温高压实验室_地球内部物质高温高压实验室_期刊论文
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Qingyou Liu,Heping Li. Electrochemical behaviour of chalcopyrite (CuFeS2) in FeCl3 solution at room temperature under differential stress[J]. International Journal of Mineral Processing,2011,98(1-2):82-88.
APA Qingyou Liu,&Heping Li.(2011).Electrochemical behaviour of chalcopyrite (CuFeS2) in FeCl3 solution at room temperature under differential stress.International Journal of Mineral Processing,98(1-2),82-88.
MLA Qingyou Liu,et al."Electrochemical behaviour of chalcopyrite (CuFeS2) in FeCl3 solution at room temperature under differential stress".International Journal of Mineral Processing 98.1-2(2011):82-88.
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