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Enhanced removal of hexavalent chromium by engineered biochar composite fabricated from phosphogypsum and distillers grains
Guoqi Lian;  Bing Wang;  Xinqing Lee;  Ling Li;  Taoze Liu;  Wenqiang Lyu
2019
发表期刊Science of the Total Environmen
卷号697页码:1-9
摘要

Two kinds of industrial wastes (distillers grains and phosphogypsum) were used as raw materials to produce a new biochar composite for Cr(VI) removal in water. The influencing factors including pyrolysis temperature, dosage, initial solution pH as well as contacting time were explored. The adsorption kinetics, isotherms, and thermodynamics of two biochars were conducted. The results show that the adsorption of Cr(VI) by biochar is related to pH. The ideal pH was 3.0 and the adsorbed Cr(VI) decreases as the pH increases. The Cr(VI) adsorption process conformed to the pseudo-second-order equation. Phosphogypsum modified (PM)-biochar is well described by the Freundlich model. The maximum adsorption capacities of distillers grains (DG)-biochar and PM-biochar on Cr(VI) were 63.1 and 157.9 mg g−1, respectively. The thermodynamic analysis indicates that the Cr(VI) adsorption occurs spontaneously which is an endothermic process. This study provided an alternative way for Cr(VI) removal from water.

关键词Pyrolysis soil Amendment biochar Amendment
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.gyig.ac.cn/handle/42920512-1/10141
专题环境地球化学国家重点实验室
作者单位1.College of Resource and Environmental Engineering, Guizhou University, Guiyang, Guizhou 550025, China
2.Key Laboratory of Karst Environment and Geohazard, Ministry of Natural Resources, Guiyang, Guizhou 550025, China
3.State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, 550081, China
4.University of Chinese Academy of Sciences, Beijing 100049, China
5.College of Eco-Environmental Engineering, Guizhou Minzu University, Guiyang 550025, China
6.Institute of Guizhou Mountain Resources, Guizhou Academy of Sciences, Guiyang 550001, China
推荐引用方式
GB/T 7714
Guoqi Lian;Bing Wang;Xinqing Lee;Ling Li;Taoze Liu;Wenqiang Lyu. Enhanced removal of hexavalent chromium by engineered biochar composite fabricated from phosphogypsum and distillers grains[J]. Science of the Total Environmen,2019,697:1-9.
APA Guoqi Lian;Bing Wang;Xinqing Lee;Ling Li;Taoze Liu;Wenqiang Lyu.(2019).Enhanced removal of hexavalent chromium by engineered biochar composite fabricated from phosphogypsum and distillers grains.Science of the Total Environmen,697,1-9.
MLA Guoqi Lian;Bing Wang;Xinqing Lee;Ling Li;Taoze Liu;Wenqiang Lyu."Enhanced removal of hexavalent chromium by engineered biochar composite fabricated from phosphogypsum and distillers grains".Science of the Total Environmen 697(2019):1-9.
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