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Pressure-induced phase transitions for goethite investigated by Raman spectroscopy and electrical conductivity
Kaixiang Liu;  Lidong Dai;  Heping Li;  Haiying Hu;  Yukai Zhuang;  Linfei Yang;  Chang Pu;  Meiling Hong
2019
发表期刊High Pressure Research
页码1-11
摘要

We reported two pressure-induced phase transitions of goethite up to ∼35 GPa using a diamond anvil cell in conjunction with ac impendence spectroscopy, Raman spectra at room temperature. The first pressure-induced phase transition at ∼7.0 GPa is manifested in noticeable changes in six Raman-active modes, two obvious splitting phenomena for the modes and the variations in the slope of conductivity. The second phase transition at ∼20 GPa was characterized by an obviously drop in electrical conductivity and the noticeable changes in the Raman-active modes. The variations in activation energy with increasing pressure were also discussed to reveal the electrical properties of goethite at high pressure.

关键词Goethite high Pressure raman Spectroscopy electrical Conductivity phase Transition
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.gyig.ac.cn/handle/42920512-1/10555
专题地球内部物质高温高压实验室
作者单位1.Key Laboratory of High-Temperature and High-Pressure Study of the Earth’s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, Guizhou, People’s Republic of China
2.University of Chinese Academy of Sciences, Beijing, People’s Republic of China
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Kaixiang Liu;Lidong Dai;Heping Li;Haiying Hu;Yukai Zhuang;Linfei Yang;Chang Pu;Meiling Hong. Pressure-induced phase transitions for goethite investigated by Raman spectroscopy and electrical conductivity[J]. High Pressure Research,2019:1-11.
APA Kaixiang Liu;Lidong Dai;Heping Li;Haiying Hu;Yukai Zhuang;Linfei Yang;Chang Pu;Meiling Hong.(2019).Pressure-induced phase transitions for goethite investigated by Raman spectroscopy and electrical conductivity.High Pressure Research,1-11.
MLA Kaixiang Liu;Lidong Dai;Heping Li;Haiying Hu;Yukai Zhuang;Linfei Yang;Chang Pu;Meiling Hong."Pressure-induced phase transitions for goethite investigated by Raman spectroscopy and electrical conductivity".High Pressure Research (2019):1-11.
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