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Raman spectroscopic study of MnAl2O4 galaxite at various pressures and temperatures
Shuangmeng Zhai;  Yuan Yin;  Sean R. Shieh;  Yun-Yuan Chang;  Tianqi Xie;  Weihong Xue
2017
发表期刊Physics and Chemistry of Minerals
卷号44期号:3页码:163–170
摘要

The vibrational properties of synthetic galaxite, MnAl2O4, were investigated at various pressures (0-29.7 GPa) and temperatures (80-973 K), respectively. The Raman frequencies of all observed bands for galaxite continuously increase with increasing pressure and decrease with increasing temperature, respectively. The quantitative analysis shows that the lowest frequency T (2g) mode has the smallest isothermal mode Gruneisen parameter. Combined with previous studies, the thermal Gruneisen parameter of galaxite is determined to be 1.23(5). The quantitative analysis of temperature dependences of Raman bands yields that the lowest frequency T (2g) mode has the largest isobaric mode Gruneisen parameter. The intrinsic anharmonic mode parameters are also calculated and nonzero, indicating an existence of intrinsic anharmonicity for MnAl2O4 spinel.

收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.gyig.ac.cn/handle/42920512-1/8178
专题地球内部物质高温高压实验室
作者单位1.Key Laboratory of High-Temperature and High-Pressure Study of the Earth’s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China
2.College of Earth Science, University of Chinese Academy of Sciences, Beijing 100049, China
3.Department of Earth Sciences, University of Western Ontario, London, ON N6A 5B7, Canada
4.Institute of Earth Sciences, Academia Sinica, Taipei 115, Taiwan
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Shuangmeng Zhai;Yuan Yin;Sean R. Shieh;Yun-Yuan Chang;Tianqi Xie;Weihong Xue. Raman spectroscopic study of MnAl2O4 galaxite at various pressures and temperatures[J]. Physics and Chemistry of Minerals,2017,44(3):163–170.
APA Shuangmeng Zhai;Yuan Yin;Sean R. Shieh;Yun-Yuan Chang;Tianqi Xie;Weihong Xue.(2017).Raman spectroscopic study of MnAl2O4 galaxite at various pressures and temperatures.Physics and Chemistry of Minerals,44(3),163–170.
MLA Shuangmeng Zhai;Yuan Yin;Sean R. Shieh;Yun-Yuan Chang;Tianqi Xie;Weihong Xue."Raman spectroscopic study of MnAl2O4 galaxite at various pressures and temperatures".Physics and Chemistry of Minerals 44.3(2017):163–170.
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